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Glycan Syntheses |
JCGG ID |
JCGG-RAC0002876 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-002876
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Regist Date |
2012/06/29 18:30:52 | ||||
| REACTANT | |||||
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Reactant Type |
tBuSH | ||||
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Reactant Type |
Et3N | ||||
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Reactant Type |
2-alkoxytetrahydropyran-2-yl radicals | ||||
| PRODUCT | |||||
MOLECULE ID |
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Product Type |
beta+beta | ||||
Yield |
76%(beta+beta/beta+alpha/alpha+beta=80/15/5) | ||||
MOLECULE ID |
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Product Type |
beta+alpha | ||||
Yield |
76%(beta+beta/beta+alpha/alpha+beta=80/15/5) | ||||
MOLECULE ID |
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Product Type |
alpha+beta | ||||
Yield |
76%(beta+beta/beta+alpha/alpha+beta=80/15/5) | ||||
| REACTION DETAIL | |||||
Reaction Time |
NOT specified | ||||
Reaction Temp |
NOT specified | ||||
Solvent |
CH2Cl2 | ||||
Reaction Type |
photochemical irradiation | ||||
Comment |
Very few were described regarding this reaction. | ||||
| COMMENT | |||||
| Keywords: diastereoselective synthesis, critical interplay, 2-deoxy-beta-glycopyranosides, beta-mannopyranosides, alpha-sialosides, alpha-glucopyranosides, beta-arabinofuranosides | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000373 | ||||
Issn |
Electronic | ||||
Doi |
10.1021/jo2017026 | ||||
PubMed ID |
21919522 | ||||
Journal Name |
The Journal of organic chemistry. (2011) 76 (22): 9193-209. | ||||
Article Title |
Methodology development and physical organic chemistry: a powerful combination for the advancement of glycochemistry. | ||||
Author |
David, Crich | ||||
Affiliation |
Department of Chemistry, Wayne State University, Detroit, Michigan 48202, USA. dcrich@chem.wayne.edu | ||||
Reference Id |
REF-0000-000374 | ||||
Source |
J. Org. Chem. 2011, 76, 9193-9209 | ||||
Doi |
10.1021/jo2017026 | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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