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Glycan Syntheses |
JCGG ID |
JCGG-RAC0002860 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-002860
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Regist Date |
2012/06/21 20:00:29 | |||||||
| REACTANT | ||||||||
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Mol |
0.35 mmol | |||||||
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Reactant Type |
Zn | |||||||
Mol |
13.4 mmol | |||||||
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Reactant Type |
AcOH | |||||||
Mol |
7.0 mmol | |||||||
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Reactant Type |
Cl3CCOCl | |||||||
Volume |
59 micro L | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
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Yield |
77% | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
40 minutes, 30 minutes | |||||||
Reaction Temp |
room temp, 0 degree C | |||||||
Solvent |
CH2Cl2 (8.7mL), pyridine (3.5mL) | |||||||
Comment |
1) 19+Zn, AcOH, 2) +Cl3CCOCl | |||||||
| COMMENT | ||||||||
| Keywords: Biantennary, N-glycans, LacNAc, LacdiNAc, SPPS | ||||||||
| There are multiple phases in this reaction. | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000371 | |||||||
Issn |
Electronic | |||||||
Doi |
10.1021/jo200149d | |||||||
PubMed ID |
21612260 | |||||||
Journal Name |
The Journal of organic chemistry. (2011) 76 (13): 5229-39. | |||||||
Article Title |
Synthesis of biantennary complex-type nonasaccharyl asn building blocks for solid-phase glycopeptide synthesis. | |||||||
Author |
Masashi, Hagiwara; Mizuki, Dohi; Yuko, Nakahara; Keiko, Komatsu; Yuya, Asahina; Akiharu, Ueki; Hironobu, Hojo; Yoshiaki, Nakahara; Yukishige, Ito | |||||||
Affiliation |
Department of Applied Biochemistry, Institute of Glycoscience, Tokai University, 4-1-1 Kitakaname, Hiratsuka-shi, Kanagawa 259-1292, Japan. | |||||||
Reference Id |
REF-0000-000372 | |||||||
Source |
J. Org. Chem. 2011, 76, 5229-5239 | |||||||
Doi |
10.1021/jo200149d | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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