JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0002778
Submitter
The Noguchi Institute
Reaction ID
R-0000-002778
Regist Date
2012/06/21 19:47:38
REACTANT
MOLECULE ID
JCGG-COM0003631 (Reaction Tree)
Mol
1.18 mmol
MOLECULE ID
JCGG-COM0000375
Reactant Type
PhCH(OMe)2
Mol
2.2 mmol
MOLECULE ID
JCGG-COM0000498
Reactant Type
p-TsOH
Mol
catalytic amount
PRODUCT
MOLECULE ID
JCGG-COM0003632 (Reaction Tree)
Yield
69%
REACTION DETAIL
Reaction Time
overnight
Reaction Temp
room temp
Solvent
dry MeCN (9mL)
COMMENT
Keywords: mannuronic acids, mannopyranosides, mannopyranosyl methyl uronate, all-cis-linked tetrasaccharide
REFERENCE
Reference Id
REF-0000-000367
Issn
Electronic
Doi
10.1021/jo201179p
PubMed ID
21793528
Journal Name
The Journal of organic chemistry. (2011) 76 (18): 7301-15.
Article Title
Stereoselective synthesis of 2,3-diamino-2,3-dideoxy-β-D-mannopyranosyl uronates.
Author
Marthe T C, Walvoort; Gert-Jan, Moggré; Gerrit, Lodder; Herman S, Overkleeft; Jeroen D C, Codée; Gijsbert A, van der Marel
Affiliation
Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.
Reference Id
REF-0000-000368
Source
J. Org. Chem. 2011, 76, 7301-7315
Doi
10.1021/jo201179p

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)