Reaction:JCGG-RAC0002771

JCGG ID

JCGG-RAC0002771

Submitter

The Noguchi Institute

Reaction ID

R-0000-002771

Regist Date

2012/06/21 19:46:58

REACTANT

MOLECULE ID

JCGG-COM0003621 (Reaction Tree)

Skeleton

JCGG-STR032525

Mol

no more than 62 mmol

MOLECULE ID

JCGG-COM0000411

Reactant Type

KOH

Mol

187 mmol

PRODUCT

MOLECULE ID

JCGG-COM0003622 (Reaction Tree)

Yield

62%(at least)

REACTION DETAIL

Reaction Time

overnight

Reaction Temp

70 degree C

Solvent

THF/MeOH = 2/3 (500mL)

COMMENT

Keywords: mannuronic acids, mannopyranosides, mannopyranosyl methyl uronate, all-cis-linked tetrasaccharide

REFERENCE

Reference Id

REF-0000-000367

Issn

Electronic

Doi

10.1021/jo201179p

PubMed ID

21793528

Journal Name

The Journal of organic chemistry. (2011) 76 (18): 7301-15.

Article Title

Stereoselective synthesis of 2,3-diamino-2,3-dideoxy-β-D-mannopyranosyl uronates.

Author

Marthe T C, Walvoort; Gert-Jan, Moggré; Gerrit, Lodder; Herman S, Overkleeft; Jeroen D C, Codée; Gijsbert A, van der Marel

Affiliation

Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.

Reference Id

REF-0000-000368

Source

J. Org. Chem. 2011, 76, 7301-7315

Doi

10.1021/jo201179p