JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0002758
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-002758
Regist Date
 2012/06/21 19:45:58
REACTANT
MOLECULE ID
 JCGG-COM0003599 (Reaction Tree)
Skeleton
JCGG-STR032527
Mol
 0.346 mmol
MOLECULE ID
 JCGG-COM0003604
Reactant Type
 succinic anhydride
Mol
 1.732 mmol
MOLECULE ID
 JCGG-COM0000047
Reactant Type
 TEA
Mol
 1.732 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0003605 (Reaction Tree)
Skeleton
JCGG-STR032527
Yield
 NOT specified
REACTION DETAIL
Reaction Time
 19 hours
Reaction Temp
 NOT specified
Solvent
 CH2Cl2 (4.7mL)
Comment
 The addition of succinic anhydride was performed before the addition of TEA.
COMMENT
Keywords: trityl, photolabile, PPGs, electron-donating substituents, m-dimethylamino, photochemical deprotection
REFERENCE
Reference Id
 REF-0000-000365
Issn
 Electronic
Doi
 10.1021/jo200692c
PubMed ID
 21612261
Journal Name
 The Journal of organic chemistry. (2011) 76 (15): 5873-81.
Article Title
 Development of trityl-based photolabile hydroxyl protecting groups.
Author
 Lei, Zhou; Haishen, Yang; Pengfei, Wang
Affiliation
 Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, Birmingham, Alabama 35294, USA.
Reference Id
 REF-0000-000366
Source
 J. Org. Chem. 2011, 76, 5873-5881
Doi
 10.1021/jo200692c
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)