JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0002727
Submitter
The Noguchi Institute
Reaction ID
R-0000-002727
Regist Date
2012/06/21 19:43:23
REACTANT
MOLECULE ID
JCGG-COM0003562 (Reaction Tree)
Mol
0.10 mmol
MOLECULE ID
JCGG-COM0000501
Reactant Type
TBDMSCl
Mol
0.20 mmol
MOLECULE ID
JCGG-COM0000759
Reactant Type
imidazole
Mol
0.30 mmol
PRODUCT
MOLECULE ID
JCGG-COM0003565 (Reaction Tree)
Yield
93%
REACTION DETAIL
Reaction Time
overnight
Reaction Temp
room temp
Solvent
CH2Cl2 (0.1mL)
COMMENT
Keywords: trityl, photolabile, PPGs, electron-donating substituents, m-dimethylamino, photochemical deprotection
The reaction is explained in text only.
REFERENCE
Reference Id
REF-0000-000365
Issn
Electronic
Doi
10.1021/jo200692c
PubMed ID
21612261
Journal Name
The Journal of organic chemistry. (2011) 76 (15): 5873-81.
Article Title
Development of trityl-based photolabile hydroxyl protecting groups.
Author
Lei, Zhou; Haishen, Yang; Pengfei, Wang
Affiliation
Department of Chemistry, University of Alabama at Birmingham, 901 14th Street South, Birmingham, Alabama 35294, USA.
Reference Id
REF-0000-000366
Source
J. Org. Chem. 2011, 76, 5873-5881
Doi
10.1021/jo200692c

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)