|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0002704 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-002704
|
||||
Regist Date |
2012/06/21 19:40:29 | ||||
| REACTANT | |||||
|
|
|
||||
Mol |
16 micro mole | ||||
|
|
|
||||
Reactant Type |
TMSONa | ||||
Mol |
71 micro mole | ||||
|
|
|
||||
Reactant Type |
palladium | ||||
Mol |
catalytic amount | ||||
|
|
|
||||
Reactant Type |
HCl (1 M aq) | ||||
Volume |
125 microL | ||||
|
|
|
||||
Reactant Type |
H2 (gas) | ||||
| PRODUCT | |||||
MOLECULE ID |
|
|
|||
Yield |
52% | ||||
| REACTION DETAIL | |||||
Reaction Time |
2.5 hours, 2 days | ||||
Reaction Temp |
NOT specified, NOT specified | ||||
Solvent |
CH2Cl2 (1.5mL), t-BuOH/H2O = 5/2 (7mL) | ||||
Comment |
1) 29+TMSONa, 2) +all the rest | ||||
| COMMENT | |||||
| Keywords: Streptococcus pneumonia, SP1, zwitterionic polysaccharide, ZPs, cis-glycosidic bond | |||||
| There are multiple phases in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000363 | ||||
Issn |
Electronic | ||||
Doi |
10.1021/jo102363d | ||||
PubMed ID |
21341806 | ||||
Journal Name |
The Journal of organic chemistry. (2011) 76 (6): 1692-706. | ||||
Article Title |
Galacturonic acid lactones in the synthesis of all trisaccharide repeating units of the zwitterionic polysaccharide Sp1. | ||||
Author |
Alphert E, Christina; Leendert J, van den Bos; Herman S, Overkleeft; Gijsbert A, van der Marel; Jeroen D C, Codée | ||||
Affiliation |
Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands. | ||||
Reference Id |
REF-0000-000364 | ||||
Source |
J. Org. Chem. 2011, 76, 1692-1706 | ||||
Doi |
10.1021/jo102363d | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
|