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Glycan Syntheses |
JCGG ID |
JCGG-RAC0002683 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-002683
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Regist Date |
2012/06/21 19:37:50 | ||||
| REACTANT | |||||
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Mol |
29.44 to 36.8 mmol | ||||
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Reactant Type |
BnBr | ||||
Mol |
110.4 mmol | ||||
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Reactant Type |
NaH (60% in mineral oil) | ||||
Mol |
110.4 mmol | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
80%(at least) | ||||
| REACTION DETAIL | |||||
Reaction Time |
overnight | ||||
Reaction Temp |
ambient temperature | ||||
Solvent |
DMF (150mL) | ||||
Comment |
The reactants were mixed at 0 degree in Celsius before stirred at ambient temperature. | ||||
| COMMENT | |||||
| Keywords: Streptococcus pneumonia, SP1, zwitterionic polysaccharide, ZPs, cis-glycosidic bond | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000363 | ||||
Issn |
Electronic | ||||
Doi |
10.1021/jo102363d | ||||
PubMed ID |
21341806 | ||||
Journal Name |
The Journal of organic chemistry. (2011) 76 (6): 1692-706. | ||||
Article Title |
Galacturonic acid lactones in the synthesis of all trisaccharide repeating units of the zwitterionic polysaccharide Sp1. | ||||
Author |
Alphert E, Christina; Leendert J, van den Bos; Herman S, Overkleeft; Gijsbert A, van der Marel; Jeroen D C, Codée | ||||
Affiliation |
Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands. | ||||
Reference Id |
REF-0000-000364 | ||||
Source |
J. Org. Chem. 2011, 76, 1692-1706 | ||||
Doi |
10.1021/jo102363d | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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