JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0002635
Submitter
The Noguchi Institute
Reaction ID
R-0000-002635
Regist Date
2012/06/21 19:33:21
REACTANT
MOLECULE ID
JCGG-COM0003425 (Reaction Tree)
Mol
6.9 mmol
MOLECULE ID
JCGG-COM0000531
Reactant Type
H2O (cold)
Volume
20 mL
MOLECULE ID
JCGG-COM0003404
Reactant Type
RuCl3*H2O
Mol
0.7 mmol
MOLECULE ID
JCGG-COM0003405
Reactant Type
NaIO4
Mol
13.8 mmol
PRODUCT
MOLECULE ID
JCGG-COM0003427 (Reaction Tree)
Product Type
intermediate
Yield
NOT specified
REACTION DETAIL
Reaction Time
2 hours
Reaction Temp
0 degree C
Solvent
CCl4/MeCN = 15mL/15mL
COMMENT
Keywords: Anthrose, Bacillus anthracis exosporium, antigenic determinants, fucose, cyclic sulfite, cyclic sulfate
The product was used for the next reaction. (without purification)
REFERENCE
Reference Id
REF-0000-000359
Issn
Electronic
Doi
10.1021/jo200340q
PubMed ID
21678952
Journal Name
The Journal of organic chemistry. (2011) 76 (15): 5985-98.
Article Title
Access to antigens related to anthrose using pivotal cyclic sulfite/sulfate intermediates.
Author
Ophélie, Milhomme; Cédric, John; Florence, Djedaïni-Pilard; Cyrille, Grandjean
Affiliation
Laboratoire des Glucides, UMR CNRS 6219, Institut de Chimie de Picardie, Université de Picardie Jules Verne, 33 rue Saint Leu, 80039 Amiens Cedex, France.
Reference Id
REF-0000-000360
Source
J. Org. Chem. 2011, 76, 5985-5998
Doi
10.1021/jo200340q

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)