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Glycan Syntheses |
JCGG ID |
JCGG-RAC0002520 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-002520
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Regist Date |
2012/06/21 19:23:02 | |||||||
| REACTANT | ||||||||
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Mol |
0.14 mmol | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
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Yield |
90% | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
2 hours | |||||||
Reaction Temp |
50 degree C | |||||||
Solvent |
dry CH2Cl2 | |||||||
Comment |
Molecular sieves AW-300 (1.6 mm pellets, 1 g) was included in the solvent. | |||||||
| The reaction was conducted under microwave irradiation. | ||||||||
| COMMENT | ||||||||
| Keywords: Methyl 1,2-Ortho Esters, 1alpha,1'beta-disaccharides, BF3*Et2O | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000349 | |||||||
Issn |
Electronic | |||||||
Doi |
10.1021/jo202335n | |||||||
PubMed ID |
22141592 | |||||||
Journal Name |
The Journal of organic chemistry. (2012) 77 (1): 795-800. | |||||||
Article Title |
Unexpected stereocontrolled access to 1α,1'β-disaccharides from methyl 1,2-ortho esters. | |||||||
Author |
Clara, Uriel; Juan, Ventura; Ana M, Gómez; J Cristóbal, López; Bert, Fraser-Reid | |||||||
Affiliation |
Instituto de Química Orgánica General (IQOG-CSIC), Juan de la Cierva 3, 28006 Madrid, Spain. | |||||||
Reference Id |
REF-0000-000350 | |||||||
Source |
J. Org. Chem. 2012, 77, 795-800 | |||||||
Doi |
10.1021/jo202335n | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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