JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0002517
Submitter
The Noguchi Institute
Reaction ID
R-0000-002517
Regist Date
2012/06/21 19:22:57
REACTANT
MOLECULE ID
JCGG-COM0003295 (Reaction Tree)
Skeleton
JCGG-STR032397
Mol
0.1 mmol
MOLECULE ID
JCGG-COM0000099
Reactant Type
BF3*OEt2
Mol
0.3 mmol
PRODUCT
MOLECULE ID
JCGG-COM0003285 (Reaction Tree)
Yield
2%
MOLECULE ID
JCGG-COM0003296 (Reaction Tree)
Skeleton
JCGG-STR032527
Yield
63%
MOLECULE ID
JCGG-COM0002519 (Reaction Tree)
Yield
8%
REACTION DETAIL
Reaction Time
10 minutes
Reaction Temp
-30 degree C
Solvent
dry CH2Cl2
COMMENT
Keywords: Methyl 1,2-Ortho Esters, 1alpha,1'beta-disaccharides, BF3*Et2O
REFERENCE
Reference Id
REF-0000-000349
Issn
Electronic
Doi
10.1021/jo202335n
PubMed ID
22141592
Journal Name
The Journal of organic chemistry. (2012) 77 (1): 795-800.
Article Title
Unexpected stereocontrolled access to 1α,1'β-disaccharides from methyl 1,2-ortho esters.
Author
Clara, Uriel; Juan, Ventura; Ana M, Gómez; J Cristóbal, López; Bert, Fraser-Reid
Affiliation
Instituto de Química Orgánica General (IQOG-CSIC), Juan de la Cierva 3, 28006 Madrid, Spain.
Reference Id
REF-0000-000350
Source
J. Org. Chem. 2012, 77, 795-800
Doi
10.1021/jo202335n

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)