|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0002434 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-002434
|
||||
Regist Date |
2012/06/21 19:13:54 | ||||
| REACTANT | |||||
|
|
|
||||
Reactant Type |
carbohydrate compound | ||||
Mol |
10 mmol | ||||
|
|
|
||||
Reactant Type |
pivaloyl chloride | ||||
Mol |
20 to 50 mmol | ||||
| PRODUCT | |||||
MOLECULE ID |
|
|
|||
Yield |
78% | ||||
| REACTION DETAIL | |||||
Reaction Time |
NOT specified | ||||
Reaction Temp |
0 degree C | ||||
Solvent |
pyridine | ||||
Comment |
pivaloyl chloride was added slowly. | ||||
| COMMENT | |||||
| Keywords: acylation, pivaloylation, pivaloyl chloride, esterifying, regioisomers | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000341 | ||||
Issn |
Electronic | ||||
PubMed ID |
11672212 | ||||
Journal Name |
The Journal of organic chemistry. (1998) 63 (17): 6035-6038. | ||||
Article Title |
Regioselective Acylation of Hexopyranosides with Pivaloyl Chloride. | ||||
Author |
Lu, Jiang; Tak-Hang, Chan | ||||
Affiliation |
Department of Chemistry, McGill University, Montréal, Québec H3A 2K6, Canada. | ||||
Reference Id |
REF-0000-000342 | ||||
Source |
J. Org. Chem. 1998, 63, 6035-6038 | ||||
Doi |
10.1021/jo980294v | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
|