|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0002429 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-002429
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Regist Date |
2012/06/21 19:13:34 | |||||||
| REACTANT | ||||||||
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|
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Mol |
1.0 equiv. | |||||||
|
|
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|||||||
Reactant Type |
thiophenol | |||||||
Mol |
1.2 equiv. | |||||||
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|
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|||||||
Reactant Type |
TMSOTf | |||||||
Mol |
0.8 equiv. | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
|
|
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Yield |
85% | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
2 hours | |||||||
Reaction Temp |
NOT specified | |||||||
Solvent |
CH2Cl2 | |||||||
Comment |
MS 4A was included in the solvent. | |||||||
| COMMENT | ||||||||
| Keywords: acylation, pivaloylation, pivaloyl chloride, esterifying, regioisomers | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000341 | |||||||
Issn |
Electronic | |||||||
PubMed ID |
11672212 | |||||||
Journal Name |
The Journal of organic chemistry. (1998) 63 (17): 6035-6038. | |||||||
Article Title |
Regioselective Acylation of Hexopyranosides with Pivaloyl Chloride. | |||||||
Author |
Lu, Jiang; Tak-Hang, Chan | |||||||
Affiliation |
Department of Chemistry, McGill University, Montréal, Québec H3A 2K6, Canada. | |||||||
Reference Id |
REF-0000-000342 | |||||||
Source |
J. Org. Chem. 1998, 63, 6035-6038 | |||||||
Doi |
10.1021/jo980294v | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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