JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0002424
Submitter
The Noguchi Institute
Reaction ID
R-0000-002424
Regist Date
2012/06/21 19:13:07
REACTANT
MOLECULE ID
JCGG-COM0003151 (Reaction Tree)
Reactant Type
sugar
Mol
0.07 mmol
MOLECULE ID
JCGG-COM0000743
Reactant Type
DDQ
Mol
0.18 mmol
PRODUCT
MOLECULE ID
JCGG-COM0003152 (Reaction Tree)
Yield
88%
REACTION DETAIL
Reaction Time
3 hours
Reaction Temp
room temp
Solvent
CH2Cl2/H2O = 10mL/0.5mL
COMMENT
Keywords: xylomannan, antifreeze, Alaskan beetle, Upis ceramboides
REFERENCE
Reference Id
REF-0000-000339
Issn
Electronic
Doi
10.1021/jo201780e
PubMed ID
21955117
Journal Name
The Journal of organic chemistry. (2011) 76 (21): 8611-20.
Article Title
Synthesis and structural verification of the xylomannan antifreeze substance from the freeze-tolerant Alaskan beetle Upis ceramboides.
Author
David, Crich; Md Yeajur, Rahaman
Affiliation
Department of Chemistry, Wayne State University, 5101 Cass Avenue, Detroit, Michigan 48202, United States. dcrich@chem.wayne.edu
Reference Id
REF-0000-000340
Source
J. Org. Chem. 2011, 76, 8611-8620
Doi
10.1021/jo201780e

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)