|
Glycan Syntheses |
JCGG ID |
JCGG-RAC0002409 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-002409
|
||||
Regist Date |
2012/06/21 19:11:34 | ||||
| REACTANT | |||||
|
|
|
||||
Reactant Type |
oligosaccharide | ||||
Mol |
0.02 mmol | ||||
|
|
|
||||
Reactant Type |
NaOMe (25% in MeOH) | ||||
Volume |
0.1 mL | ||||
|
|
|
||||
Reactant Type |
Pd-C | ||||
Weight |
20 mg | ||||
|
|
|
||||
Reactant Type |
glacial AcOH | ||||
Mol |
1 drop | ||||
|
|
|
||||
Reactant Type |
H2 (gas, 40 psi) | ||||
| PRODUCT | |||||
MOLECULE ID |
|
|
|||
Yield |
94% | ||||
| REACTION DETAIL | |||||
Reaction Time |
NOT specified, 12 hours | ||||
Reaction Temp |
0 degree C, room temp | ||||
Solvent |
MeOH, MeOH | ||||
Comment |
1) oligosaccharide+NaOMe, 2) +all the rest | ||||
| COMMENT | |||||
| Keywords: xylomannan, antifreeze, Alaskan beetle, Upis ceramboides | |||||
| There are multiple phases in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000339 | ||||
Issn |
Electronic | ||||
Doi |
10.1021/jo201780e | ||||
PubMed ID |
21955117 | ||||
Journal Name |
The Journal of organic chemistry. (2011) 76 (21): 8611-20. | ||||
Article Title |
Synthesis and structural verification of the xylomannan antifreeze substance from the freeze-tolerant Alaskan beetle Upis ceramboides. | ||||
Author |
David, Crich; Md Yeajur, Rahaman | ||||
Affiliation |
Department of Chemistry, Wayne State University, 5101 Cass Avenue, Detroit, Michigan 48202, United States. dcrich@chem.wayne.edu | ||||
Reference Id |
REF-0000-000340 | ||||
Source |
J. Org. Chem. 2011, 76, 8611-8620 | ||||
Doi |
10.1021/jo201780e | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
|