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Glycan Syntheses |
JCGG ID |
JCGG-RAC0002404 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-002404
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Regist Date |
2012/06/21 19:10:29 | ||||
| REACTANT | |||||
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Reactant Type |
oligosaccharide | ||||
Mol |
0.1 mmol | ||||
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Reactant Type |
NaBH3CN | ||||
Mol |
0.5 mmol | ||||
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Reactant Type |
HCl | ||||
Volume |
1.5 mL | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
87% | ||||
| REACTION DETAIL | |||||
Reaction Time |
1 hour, until effervescence ceased | ||||
Reaction Temp |
0 degree C, room temp | ||||
Solvent |
THF, THF | ||||
Comment |
1) +all except HCl, 2) +HCl | ||||
| HCl was added dropwise and very slowly. | |||||
| MS 3A was included in the solvent. | |||||
| COMMENT | |||||
| Keywords: xylomannan, antifreeze, Alaskan beetle, Upis ceramboides | |||||
| There are multiple phases in this reaction. | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000339 | ||||
Issn |
Electronic | ||||
Doi |
10.1021/jo201780e | ||||
PubMed ID |
21955117 | ||||
Journal Name |
The Journal of organic chemistry. (2011) 76 (21): 8611-20. | ||||
Article Title |
Synthesis and structural verification of the xylomannan antifreeze substance from the freeze-tolerant Alaskan beetle Upis ceramboides. | ||||
Author |
David, Crich; Md Yeajur, Rahaman | ||||
Affiliation |
Department of Chemistry, Wayne State University, 5101 Cass Avenue, Detroit, Michigan 48202, United States. dcrich@chem.wayne.edu | ||||
Reference Id |
REF-0000-000340 | ||||
Source |
J. Org. Chem. 2011, 76, 8611-8620 | ||||
Doi |
10.1021/jo201780e | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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