JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0002314
Submitter
The Noguchi Institute
Reaction ID
R-0000-002314
Regist Date
2012/06/21 19:01:34
REACTANT
MOLECULE ID
JCGG-COM0003018 (Reaction Tree)
MOLECULE ID
JCGG-COM0002663
Reactant Type
HP(O)(OMe)2
MOLECULE ID
JCGG-COM0001377
Reactant Type
t-BuOK
PRODUCT
MOLECULE ID
JCGG-COM0003019 (Reaction Tree)
Yield
NOT specified
REACTION DETAIL
Reaction Time
2 hours
Reaction Temp
0 degree C
Solvent
PhCH3
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: 2-acylamino uronic acid, glycosyl phosphonates, oxidation, uronate 2-nitro-glycal, thermodynamic 1,2-trans-di-equatorial phosphonylation
REFERENCE
Reference Id
REF-0000-000331
Issn
Electronic
Doi
10.1021/jo2002193
PubMed ID
21495699
Journal Name
The Journal of organic chemistry. (2011) 76 (10): 4099-104.
Article Title
Accessing C-1 phosphonylated 2-acylamino uronic acids via 2-nitro-glycals.
Author
Beenu, Bhatt; Robin J, Thomson; Mark, von Itzstein
Affiliation
Institute for Glycomics, Griffith University, Gold Coast Campus, Queensland 4222, Australia.
Reference Id
REF-0000-000332
Source
J. Org. Chem. 2011, 76, 4099-4104
Doi
10.1021/jo2002193

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