JCGG ID |
JCGG-RAC0002232 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-002232 | |||||||
Regist Date |
2012/06/21 18:52:48 | |||||||
REACTANT | ||||||||
|
|
|||||||
Mol |
0.88 mmol | |||||||
|
|
|||||||
Reactant Type |
PhSH | |||||||
Mol |
2.63 mmol | |||||||
|
|
|||||||
Reactant Type |
DIPEA | |||||||
Mol |
0.88 mmol | |||||||
PRODUCT | ||||||||
MOLECULE ID |
|
|
||||||
Product Type |
alpha | |||||||
Yield |
80%(alpha/beta=2/1) | |||||||
MOLECULE ID |
|
|
|
|||||
Product Type |
beta | |||||||
Yield |
80%(alpha/beta=2/1) | |||||||
REACTION DETAIL | ||||||||
Reaction Time |
1 hour | |||||||
Reaction Temp |
0 degree C | |||||||
Solvent |
MeCN | |||||||
COMMENT | ||||||||
Keywords: stereoselectivity, 2-azido-2-deoxygalactosyl donors, acetyl groups, temperature, computational methods | ||||||||
REFERENCE | ||||||||
Reference Id |
REF-0000-000327 | |||||||
Issn |
Electronic | |||||||
Doi |
10.1021/jo1025157 | |||||||
PubMed ID |
21574599 | |||||||
Journal Name |
The Journal of organic chemistry. (2011) 76 (13): 5207-18. | |||||||
Article Title |
Study of the stereoselectivity of 2-azido-2-deoxygalactosyl donors: remote protecting group effects and temperature dependency. | |||||||
Author |
Jane, Kalikanda; Zhitao, Li | |||||||
Affiliation |
Department of Chemistry, Binghamton University, Binghamton, New York 13902, United States. | |||||||
Reference Id |
REF-0000-000328 | |||||||
Source |
J. Org. Chem. 2011, 76, 5207-5218 | |||||||
Doi |
10.1021/jo1025157 |
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST) |