JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0002125
Submitter
The Noguchi Institute
Reaction ID
R-0000-002125
Regist Date
2012/06/21 18:36:38
REACTANT
MOLECULE ID
JCGG-COM0002769 (Reaction Tree)
Skeleton
JCGG-STR015611
Mol
1 equiv.
MOLECULE ID
JCGG-COM0002770
Reactant Type
oleic acid
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000652
Reactant Type
DCC
Mol
1 equiv.
MOLECULE ID
JCGG-COM0000500
Reactant Type
DMAP
Mol
0.02 equiv.
PRODUCT
MOLECULE ID
JCGG-COM0002771 (Reaction Tree)
Skeleton
JCGG-STR015611
Yield
12%
MOLECULE ID
JCGG-COM0002772 (Reaction Tree)
Skeleton
JCGG-STR015611
Yield
3%
REACTION DETAIL
Reaction Time
18 hours
Reaction Temp
0 degree C to room temp then 60 degree C
Solvent
PhCH3 (0.4 mL per 0.1 g of compound 4)
Comment
3 A molecular sieve was included in the solvent.
COMMENT
Keywords: maradolipid, C. elegans, trehalose
REFERENCE
Reference Id
REF-0000-000319
Issn
Electronic
Doi
10.1021/jo200979n
PubMed ID
21739985
Journal Name
The Journal of organic chemistry. (2011) 76 (16): 6866-70.
Article Title
Synthesis of maradolipid.
Author
Vikram A, Sarpe; Suvarn S, Kulkarni
Affiliation
Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400076, India.
Reference Id
REF-0000-000320
Source
J. Org. Chem. 2011, 76, 6866-6870
Doi
10.1021/jo200979n

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)