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Glycan Syntheses |
JCGG ID |
JCGG-RAC0002120 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-002120
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Regist Date |
2012/06/21 18:36:07 | |||||||
| REACTANT | ||||||||
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Reactant Type |
trehalose | |||||||
Mol |
3.27 mmol | |||||||
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Reactant Type |
TMSCl | |||||||
Mol |
39.26 + 13.08 mmol | |||||||
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Reactant Type |
TEA | |||||||
Mol |
130.9 mmol | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
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Yield |
quantitative(probably) | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
12 + 4 hours | |||||||
Reaction Temp |
room temp | |||||||
Solvent |
CH2Cl2 | |||||||
Comment |
TMSCl was added twice. (0 hour, 12 hours) | |||||||
| The reaction mixture was cooled to 0 degree in Celsius each time when the addition of TMSCl was performed. | ||||||||
| COMMENT | ||||||||
| Keywords: maradolipid, C. elegans, trehalose | ||||||||
| Compound 3 showed no impurity peaks in 1H and 13C NMR spectrum | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000319 | |||||||
Issn |
Electronic | |||||||
Doi |
10.1021/jo200979n | |||||||
PubMed ID |
21739985 | |||||||
Journal Name |
The Journal of organic chemistry. (2011) 76 (16): 6866-70. | |||||||
Article Title |
Synthesis of maradolipid. | |||||||
Author |
Vikram A, Sarpe; Suvarn S, Kulkarni | |||||||
Affiliation |
Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400076, India. | |||||||
Reference Id |
REF-0000-000320 | |||||||
Source |
J. Org. Chem. 2011, 76, 6866-6870 | |||||||
Doi |
10.1021/jo200979n | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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