JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0002103
Submitter
The Noguchi Institute
Reaction ID
R-0000-002103
Regist Date
2012/06/21 18:34:57
REACTANT
MOLECULE ID
JCGG-COM0002755 (Reaction Tree)
Skeleton
JCGG-STR032526
Mol
0.14 mmol
MOLECULE ID
JCGG-COM0002717
Reactant Type
(Me3Si)2S
Mol
0.14 mmol
MOLECULE ID
JCGG-COM0000009
Reactant Type
TMSOTf
Mol
0.02 mmol
PRODUCT
MOLECULE ID
JCGG-COM0002756 (Reaction Tree)
Product Type
beta
Yield
50%
REACTION DETAIL
Reaction Time
1 hour
Reaction Temp
0 degree C
Solvent
CH2Cl2
COMMENT
Keywords: glycosylthiols, bis-trimethyl-silyl sulfide, sterically hindered S-nucleophile
REFERENCE
Reference Id
REF-0000-000317
Issn
Electronic
Doi
10.1021/jo200624e
PubMed ID
21800823
Journal Name
The Journal of organic chemistry. (2011) 76 (18): 7539-45.
Article Title
Synthesis of glycosylthiols and reactivity studies.
Author
Ravindra T, Dere; Amit, Kumar; Vipin, Kumar; Xiangming, Zhu; Richard R, Schmidt
Affiliation
Fachbereich Chemie, Universita?t Konstanz, Fach 725, D-78457 Konstanz, Germany.
Reference Id
REF-0000-000318
Source
J. Org. Chem. 2011, 76, 7539-7545
Doi
10.1021/jo200624e

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)