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Glycan Syntheses |
JCGG ID |
JCGG-RAC0002084 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-002084
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Regist Date |
2012/06/21 18:32:51 | ||||
| REACTANT | |||||
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Mol |
0.46 mmol | ||||
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||||
Reactant Type |
(Me3Si)2S | ||||
Mol |
0.69 mmol | ||||
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||||
Reactant Type |
TMSOTf | ||||
Mol |
0.23 mmol | ||||
| PRODUCT | |||||
MOLECULE ID |
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Product Type |
alpha | ||||
Yield |
56%(alpha/beta=64/36) | ||||
MOLECULE ID |
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Product Type |
beta | ||||
Yield |
56%(alpha/beta=64/36) | ||||
| REACTION DETAIL | |||||
Reaction Time |
3 hours | ||||
Reaction Temp |
0 degree C | ||||
Solvent |
CH2Cl2 | ||||
| COMMENT | |||||
| Keywords: glycosylthiols, bis-trimethyl-silyl sulfide, sterically hindered S-nucleophile | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000317 | ||||
Issn |
Electronic | ||||
Doi |
10.1021/jo200624e | ||||
PubMed ID |
21800823 | ||||
Journal Name |
The Journal of organic chemistry. (2011) 76 (18): 7539-45. | ||||
Article Title |
Synthesis of glycosylthiols and reactivity studies. | ||||
Author |
Ravindra T, Dere; Amit, Kumar; Vipin, Kumar; Xiangming, Zhu; Richard R, Schmidt | ||||
Affiliation |
Fachbereich Chemie, Universita？t Konstanz, Fach 725, D-78457 Konstanz, Germany. | ||||
Reference Id |
REF-0000-000318 | ||||
Source |
J. Org. Chem. 2011, 76, 7539-7545 | ||||
Doi |
10.1021/jo200624e | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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