JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0002080
Submitter
The Noguchi Institute
Reaction ID
R-0000-002080
Regist Date
2012/06/21 18:32:22
REACTANT
MOLECULE ID
JCGG-COM0000315 (Reaction Tree)
MOLECULE ID
JCGG-COM0002717
Reactant Type
(Me3Si)2S
MOLECULE ID
JCGG-COM0000009
Reactant Type
TMSOTf
PRODUCT
MOLECULE ID
JCGG-COM0002718 (Reaction Tree)
Product Type
alpha
Yield
NOT specified
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
NOT specified
Solvent
CH2Cl2
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: glycosylthiols, bis-trimethyl-silyl sulfide, sterically hindered S-nucleophile
The procedure regarding this reaction is discussed in another paper in References.
REFERENCE
Reference Id
REF-0000-000317
Issn
Electronic
Doi
10.1021/jo200624e
PubMed ID
21800823
Journal Name
The Journal of organic chemistry. (2011) 76 (18): 7539-45.
Article Title
Synthesis of glycosylthiols and reactivity studies.
Author
Ravindra T, Dere; Amit, Kumar; Vipin, Kumar; Xiangming, Zhu; Richard R, Schmidt
Affiliation
Fachbereich Chemie, Universita?t Konstanz, Fach 725, D-78457 Konstanz, Germany.
Reference Id
REF-0000-000318
Source
J. Org. Chem. 2011, 76, 7539-7545
Doi
10.1021/jo200624e

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)