Reaction:JCGG-RAC0001984

JCGG ID		JCGG-RAC0001984
Submitter		The Noguchi Institute
Reaction ID		R-0000-001984
Regist Date		2012/06/21 18:20:54
REACTANT
MOLECULE ID		JCGG-COM0002206 (Reaction Tree)
	Reactant Type	trichloroacetimidate
	Mol	4.0 mmol
MOLECULE ID		JCGG-COM0002207 (Reaction Tree)
	Reactant Type	acceptor
	Mol	4.5 mmol
MOLECULE ID		JCGG-COM0000009
	Reactant Type	TMSOTf
	Mol	40 micro mole
MOLECULE ID		JCGG-COM0000549
	Reactant Type	NaHCO3 (solid)
	Weight	0.5 g
PRODUCT
MOLECULE ID		JCGG-COM0002208 (Reaction Tree)
	Yield	80%
REACTION DETAIL
Reaction Time		10 minutes
Reaction Temp		-40 degree C
Solvent		dry MeCN
COMMENT
Keywords: synthesis, glycosylation strategies, block synthesis, LewisX dimer intermediate
REFERENCE
Reference Id		REF-0000-000253
	Source	Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id		REF-0000-000254
	Source	ISBN 978-3-527-31528-4
Reference Id		REF-0000-000310
	Source	Tetrahedron Lett. 38, 1173 (1997)