JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001960
Submitter
The Noguchi Institute
Reaction ID
R-0000-001960
Regist Date
2012/06/21 18:18:30
REACTANT
MOLECULE ID
JCGG-COM0002556 (Reaction Tree)
MOLECULE ID
JCGG-COM0002557
Reactant Type
Tebbe's reagent
PRODUCT
MOLECULE ID
JCGG-COM0002558 (Reaction Tree)
Yield
90%
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
-40 to 15 degree C
Solvent
THF/PhCH3/pyridine
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: synthesis, beta-mannopyranosides, intramolecular aglycone delivery, IAD, Tebbe's reagent
The reaction is the 2nd part of the sequence.
REFERENCE
Reference Id
REF-0000-000253
Source
Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
REF-0000-000254
Source
ISBN 978-3-527-31528-4
Reference Id
REF-0000-000302
Source
Can. J. Chem. 72, 1447 (1994)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)