JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001959
Submitter
The Noguchi Institute
Reaction ID
R-0000-001959
Regist Date
2012/06/21 18:18:23
REACTANT
MOLECULE ID
JCGG-COM0001659 (Reaction Tree)
Skeleton
JCGG-STR032397
MOLECULE ID
JCGG-COM0001015
Reactant Type
EtSH
MOLECULE ID
JCGG-COM0000099
Reactant Type
BF3*OEt2
PRODUCT
MOLECULE ID
JCGG-COM0002556 (Reaction Tree)
Yield
84%
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
NOT specified
Solvent
NOT specified
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: synthesis, beta-mannopyranosides, intramolecular aglycone delivery, IAD, Tebbe's reagent
The reaction is the 1st part of the sequence.
REFERENCE
Reference Id
REF-0000-000253
Source
Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
REF-0000-000254
Source
ISBN 978-3-527-31528-4
Reference Id
REF-0000-000302
Source
Can. J. Chem. 72, 1447 (1994)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)