JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001928
Submitter
The Noguchi Institute
Reaction ID
R-0000-001928
Regist Date
2012/06/21 18:15:48
REACTANT
MOLECULE ID
JCGG-COM0002525 (Reaction Tree)
Skeleton
JCGG-STR018184
MOLECULE ID
JCGG-COM0000043 (Reaction Tree)
Skeleton
JCGG-STR032526
MOLECULE ID
JCGG-COM0000002
Reactant Type
Yb(OTf)3
PRODUCT
MOLECULE ID
JCGG-COM0002526 (Reaction Tree)
Skeleton
JCGG-STR002894
Yield
55%(at least)
REACTION DETAIL
Reaction Time
5 hours
Reaction Temp
-30 degree C to room temp
Solvent
MeCN
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: synthesis, trichloroacetimidate method, Yb(OTf)3
The reaction is the 2nd part of the sequence.
REFERENCE
Reference Id
REF-0000-000253
Source
Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
REF-0000-000254
Source
ISBN 978-3-527-31528-4
Reference Id
REF-0000-000297
Source
Synlett 583 (2006)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)