JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001926
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001926
Regist Date
 2012/06/21 18:15:33
REACTANT
MOLECULE ID
 JCGG-COM0002520 (Reaction Tree)
Skeleton
JCGG-STR032527
Reactant Type
 donor
Mol
 2.14 mmol
MOLECULE ID
 JCGG-COM0002522 (Reaction Tree)
Skeleton
JCGG-STR032525
Reactant Type
 acceptor
Mol
 0.047 mmol
MOLECULE ID
 JCGG-COM0000009
Reactant Type
 TMSOTf (5% in CH2Cl2)
Volume
 0.2 mL
PRODUCT
MOLECULE ID
 JCGG-COM0002523 (Reaction Tree)
Yield
 quantitative
REACTION DETAIL
Reaction Time
 overnight
Reaction Temp
 room temp
Solvent
 dry CH2Cl2
Comment
 The reactants were mixed at 0 degree in Celsius before stirred at room temperature.
COMMENT
Keywords: synthesis, trichloroacetimidate method, TMSOTf
REFERENCE
Reference Id
 REF-0000-000253
Source
 Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
 REF-0000-000254
Source
 ISBN 978-3-527-31528-4
Reference Id
 REF-0000-000292
Source
 Org. Biomol. Chem. 4, 3901 (2006)
Reference Id
 REF-0000-000296
Source
 Carbohydr. Res. 310, 35 (1999)
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)