Reaction:JCGG-RAC0001925

JCGG ID

JCGG-RAC0001925

Submitter

The Noguchi Institute

Reaction ID

R-0000-001925

Regist Date

2012/06/21 18:15:06

REACTANT

MOLECULE ID

JCGG-COM0002521 (Reaction Tree)

Skeleton

JCGG-STR032526

Reactant Type

donor

Mol

4.42 mmol

MOLECULE ID

JCGG-COM0002204 (Reaction Tree)

Reactant Type

acceptor

Mol

2.21 mmol

MOLECULE ID

JCGG-COM0000009

Reactant Type

TMSOTf (in 1.5 mL of Et2O)

Mol

50 micromole

PRODUCT

MOLECULE ID

JCGG-COM0002205 (Reaction Tree)

Yield

75%

REACTION DETAIL

Reaction Time

more than 5 hours

Reaction Temp

-20 degree C

Solvent

dry Et2O

Comment

TMSOTf was added dropwise.

COMMENT

Keywords: synthesis, trichloroacetimidate method, TMSOTf

REFERENCE

Reference Id

REF-0000-000253

Source

Essentials of Carbohydrate Chemistry and Biochemistry

Reference Id

REF-0000-000254

Source

ISBN 978-3-527-31528-4

Reference Id

REF-0000-000295

Source

Liebigs Ann. Chem. 1826 (1984)