JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001923
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001923
Regist Date
 2012/06/21 18:14:59
REACTANT
MOLECULE ID
 JCGG-COM0002519 (Reaction Tree)
Mol
 33.5 mmol
MOLECULE ID
 JCGG-COM0000522
Reactant Type
 DBU
Mol
 3.40 mmol
MOLECULE ID
 JCGG-COM0000521
Reactant Type
 Cl3CCN
Mol
 unknown
PRODUCT
MOLECULE ID
 JCGG-COM0002520 (Reaction Tree)
Skeleton
JCGG-STR032527
Yield
 97%
REACTION DETAIL
Reaction Time
 2 hours, 10 hours
Reaction Temp
 0 degree C, room temp
Solvent
 dry CH2Cl2, dry CH2Cl2
Comment
 1) +all, 2) temperature change
COMMENT
Keywords: synthesis, trichloroacetimidate method, DBU
ATTENTION: Cl3CCN appearing in the scheme is not mentioned in the written method.
There are multiple steps in this reaction.
REFERENCE
Reference Id
 REF-0000-000253
Source
 Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
 REF-0000-000254
Source
 ISBN 978-3-527-31528-4
Reference Id
 REF-0000-000292
Source
 Org. Biomol. Chem. 4, 3901 (2006)
Reference Id
 REF-0000-000293
Source
 Tetrahedron Asym. 9, 781 (1998)
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)