Reaction:JCGG-RAC0001915

JCGG ID		JCGG-RAC0001915
Submitter		The Noguchi Institute
Reaction ID		R-0000-001915
Regist Date		2012/06/21 18:14:31
REACTANT
MOLECULE ID		JCGG-COM0002513 (Reaction Tree)
	Reactant Type	donor (in 10 mL of nitromethane)
	Mol	3.37 mmol
MOLECULE ID		JCGG-COM0002514 (Reaction Tree)
	Reactant Type	acceptor
	Mol	2.86 mmol
MOLECULE ID		JCGG-COM0000625
	Reactant Type	collidine
	Weight	408 mg
MOLECULE ID		JCGG-COM0000624
	Reactant Type	AgOTf
	Weight	870 mg
PRODUCT
MOLECULE ID		JCGG-COM0002515 (Reaction Tree)
	Yield	78%
REACTION DETAIL
Reaction Time		more than 3 hours
Reaction Temp		-30 degree C
Solvent		dry nitromethane
Comment		The addition of the donor was performed after the addition of all the other reactants.
		The donor was added dropwise.
		The reaction mixture was gradually allowed to warm to room temperature at the end of the reaction.
COMMENT
Keywords: synthesis, Koenigs-Knorr method, silver triflate
REFERENCE
Reference Id		REF-0000-000253
	Source	Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id		REF-0000-000254
	Source	ISBN 978-3-527-31528-4
Reference Id		REF-0000-000291
	Source	Doctoral Thesis, University of Hamburg (1980)