Reaction:JCGG-RAC0001912

JCGG ID

JCGG-RAC0001912

Submitter

The Noguchi Institute

Reaction ID

R-0000-001912

Regist Date

2012/06/21 18:14:11

REACTANT

MOLECULE ID

JCGG-COM0001261 (Reaction Tree)

Skeleton

JCGG-STR031569

Mol

25.6 mmol

MOLECULE ID

JCGG-COM0002509

Reactant Type

2-bromethanol

Mol

30.7 mmol

MOLECULE ID

JCGG-COM0000099

Reactant Type

BF3*OEt2

Mol

128 mmol

PRODUCT

MOLECULE ID

JCGG-COM0002510 (Reaction Tree)

Skeleton

JCGG-STR031569

Yield

60%

REACTION DETAIL

Reaction Time

25 minutes + 1 hour, 12 hours

Reaction Temp

0 degree C, room temp

Solvent

dry CH2Cl2, dry CH2Cl2

Comment

1) +all, 2) temperature change

BF3*OEt2 was added dropwise over 25 minutes.

The reaction was conducted in dark condition.

COMMENT

Keywords: synthesis, (2-bromoethyl)2,3,4,6-tetra-O-acetyl-beta-D-glucopyranoside

There are multiple steps in this reaction.

REFERENCE

Reference Id

REF-0000-000253

Source

Essentials of Carbohydrate Chemistry and Biochemistry

Reference Id

REF-0000-000254

Source

ISBN 978-3-527-31528-4

Reference Id

REF-0000-000289

Source

Carbohydr. Res. 116, 303 (1983)