JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001907
Submitter
The Noguchi Institute
Reaction ID
R-0000-001907
Regist Date
2012/06/21 18:13:45
REACTANT
MOLECULE ID
JCGG-COM0002389 (Reaction Tree)
Skeleton
JCGG-STR032527
Reactant Type
allyl alpha-D-mannopyranose
MOLECULE ID
JCGG-COM0002463
Reactant Type
PhC(OEt)3
MOLECULE ID
JCGG-COM0000498
Reactant Type
p-TsOH
MOLECULE ID
JCGG-COM0000110
Reactant Type
TFA
PRODUCT
MOLECULE ID
JCGG-COM0002503 (Reaction Tree)
Skeleton
JCGG-STR032527
Yield
45%(at least)
REACTION DETAIL
Reaction Time
2 hours
Reaction Temp
room temp
Solvent
MeCN
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: synthesis, allyl alpha-D-mannoside
The reaction is the 1st part of the sequence.
REFERENCE
Reference Id
REF-0000-000253
Source
Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
REF-0000-000254
Source
ISBN 978-3-527-31528-4

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)