JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001900
Submitter
The Noguchi Institute
Reaction ID
R-0000-001900
Regist Date
2012/06/21 18:13:14
REACTANT
MOLECULE ID
JCGG-COM0002495 (Reaction Tree)
MOLECULE ID
JCGG-COM0001169
Reactant Type
TBDMSOTf
MOLECULE ID
JCGG-COM0000979
Reactant Type
pyridine
PRODUCT
MOLECULE ID
JCGG-COM0002496 (Reaction Tree)
Product Type
intermediate 1
Yield
78% to 97%
REACTION DETAIL
Reaction Time
4 hours
Reaction Temp
0 to 20 degree C
Solvent
CH2Cl2
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: synthesis, carbohydrate scaffolds, orthogonality
The reaction is the 3rd part of the sequence.
REFERENCE
Reference Id
REF-0000-000253
Source
Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
REF-0000-000254
Source
ISBN 978-3-527-31528-4
Reference Id
REF-0000-000288
Source
Angew. Chem. Int. Ed. 43, 1104 (2004)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)