JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001899
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001899
Regist Date
 2012/06/21 18:13:10
REACTANT
MOLECULE ID
 JCGG-COM0002493 (Reaction Tree)
Reactant Type
 intermediate 2
MOLECULE ID
 JCGG-COM0002494
Reactant Type
 anisaldehyde dimethyl acetal
MOLECULE ID
 JCGG-COM0000498
Reactant Type
 p-TsOH
PRODUCT
MOLECULE ID
 JCGG-COM0002495 (Reaction Tree)
Yield
 30% to 55%(at least)
REACTION DETAIL
Reaction Time
 6 hours
Reaction Temp
 50 degree C
Solvent
 DMF
Comment
 Very few were described regarding this reaction.
COMMENT
Keywords: synthesis, carbohydrate scaffolds, orthogonality
The reaction is the 2nd part of the sequence.
REFERENCE
Reference Id
 REF-0000-000253
Source
 Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
 REF-0000-000254
Source
 ISBN 978-3-527-31528-4
Reference Id
 REF-0000-000288
Source
 Angew. Chem. Int. Ed. 43, 1104 (2004)
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)