JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001889
Submitter
The Noguchi Institute
Reaction ID
R-0000-001889
Regist Date
2012/06/21 18:12:18
REACTANT
MOLECULE ID
JCGG-COM0002478 (Reaction Tree)
Skeleton
JCGG-STR032397
MOLECULE ID
JCGG-COM0000634
Reactant Type
NaN3
PRODUCT
MOLECULE ID
JCGG-COM0002479 (Reaction Tree)
Skeleton
JCGG-STR025230
Yield
86%
REACTION DETAIL
Reaction Time
NOT specified
Reaction Temp
NOT specified
Solvent
DMF
Comment
Very few were described regarding this reaction.
COMMENT
Keywords: synthesis, N-protection, amino sugars, trifluoromethanesulfonate derivatives, azidonitration
The reaction is the 2nd part of the sequence.
Epimerization at C-2 occurred.
REFERENCE
Reference Id
REF-0000-000253
Source
Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
REF-0000-000254
Source
ISBN 978-3-527-31528-4

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)