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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001880 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001880
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Regist Date |
2012/06/21 18:11:26 | |||||||
| REACTANT | ||||||||
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Reactant Type |
intermediate 1 | |||||||
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Reactant Type |
BzCl (in pyridine) | |||||||
Volume |
4 mL | |||||||
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Reactant Type |
pyridine | |||||||
Volume |
20 mL | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
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Product Type |
intermediate 2 | |||||||
Yield |
70%(at least) | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
NOT specified | |||||||
Reaction Temp |
room temp | |||||||
Solvent |
dry CH2Cl2 | |||||||
Comment |
The reactants were mixed at 0 degree in Celsius before stirred at room temperature. | |||||||
| BzCl was added dropwise. | ||||||||
| COMMENT | ||||||||
| Keywords: synthesis, orthoesters, 2,4-di-O-benzoyl-6-deoxy-alpha-L-galactopyranoside, triethyl orthobenzoate | ||||||||
| All the synthetic sequence took place in the same reaction vessel. | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000253 | |||||||
Source |
Essentials of Carbohydrate Chemistry and Biochemistry | |||||||
Reference Id |
REF-0000-000254 | |||||||
Source |
ISBN 978-3-527-31528-4 | |||||||
Reference Id |
REF-0000-000284 | |||||||
Source |
Liebigs Ann. Chem. 1237 (1990) | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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