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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001855 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001855
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Regist Date |
2012/06/21 18:09:20 | |||||||
| REACTANT | ||||||||
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Reactant Type |
Ph2BBr | |||||||
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Reactant Type |
BH3 | |||||||
| PRODUCT | ||||||||
MOLECULE ID |
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Yield |
88% | |||||||
| REACTION DETAIL | ||||||||
Reaction Time |
NOT specified, NOT specified | |||||||
Reaction Temp |
-78 degree C, -78 to -20 degree C | |||||||
Solvent |
Et3N, THF | |||||||
Comment |
1) +all except BH3, 2) +BH3 | |||||||
| Very few were described regarding this reaction. | ||||||||
| COMMENT | ||||||||
| Keywords: regioselective cleavage, 4,6-O-benzylidenated glycosides | ||||||||
| There are multiple steps in this reaction. | ||||||||
| REFERENCE | ||||||||
Reference Id |
REF-0000-000253 | |||||||
Source |
Essentials of Carbohydrate Chemistry and Biochemistry | |||||||
Reference Id |
REF-0000-000254 | |||||||
Source |
ISBN 978-3-527-31528-4 | |||||||
Reference Id |
REF-0000-000276 | |||||||
Source |
Can. J. Chem. 68, 897 (1990) | |||||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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