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Glycan Syntheses |
JCGG ID |
JCGG-RAC0001854 | ||||
Submitter |
The Noguchi Institute | ||||
Reaction ID |
R-0000-001854
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Regist Date |
2012/06/21 18:09:10 | ||||
| REACTANT | |||||
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Reactant Type |
Et3SiH | ||||
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Reactant Type |
TFA | ||||
| PRODUCT | |||||
MOLECULE ID |
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Yield |
85% | ||||
| REACTION DETAIL | |||||
Reaction Time |
5 hours | ||||
Reaction Temp |
0 degree C | ||||
Solvent |
CH2Cl2 | ||||
Comment |
Very few were described regarding this reaction. | ||||
| COMMENT | |||||
| Keywords: regioselective cleavage, 4,6-O-benzylidenated glycosides | |||||
| REFERENCE | |||||
Reference Id |
REF-0000-000253 | ||||
Source |
Essentials of Carbohydrate Chemistry and Biochemistry | ||||
Reference Id |
REF-0000-000254 | ||||
Source |
ISBN 978-3-527-31528-4 | ||||
Reference Id |
REF-0000-000273 | ||||
Source |
J. Am. Chem. Soc. 125, 6149 (2003) | ||||
Reference Id |
REF-0000-000274 | ||||
Source |
Tetrahedron Lett. 36, 669 (1995) | ||||
Reference Id |
REF-0000-000275 | ||||
Source |
Tetrahedron Lett. 39, 355 (1998) | ||||
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)
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