JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001843
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001843
Regist Date
 2012/06/21 18:08:18
REACTANT
MOLECULE ID
 JCGG-COM0002415 (Reaction Tree)
Skeleton
JCGG-STR032525
Reactant Type
 stannane
Mol
 21.1 to 25.7 mmol
MOLECULE ID
 JCGG-COM0000161
Reactant Type
 BnBr
Volume
 40 mL
MOLECULE ID
 JCGG-COM0002100
Reactant Type
 NaH
Mol
 unknown
PRODUCT
MOLECULE ID
 JCGG-COM0002416 (Reaction Tree)
Skeleton
JCGG-STR032525
Yield
 82%(at least)
REACTION DETAIL
Reaction Time
 16 hours
Reaction Temp
 90 degree C
Solvent
 DMF
COMMENT
Keywords: synthesis, methyl 2,6-di-O-benzyl-alpha-D-glucopyranoside
The reaction is the 2nd part of the sequence.
ATTENTION: NaH appearing in the scheme is not mentioned in the written method.
ATTENTION: DMF (solvent) appearing in the scheme is not mentioned in the written method.
REFERENCE
Reference Id
 REF-0000-000253
Source
 Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
 REF-0000-000254
Source
 ISBN 978-3-527-31528-4
Reference Id
 REF-0000-000267
Source
 Tetrahedron Lett. 11, 3503 (1976)
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)