JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001825
Submitter
The Noguchi Institute
Reaction ID
R-0000-001825
Regist Date
2012/06/21 18:06:36
REACTANT
MOLECULE ID
JCGG-COM0002386 (Reaction Tree)
Skeleton
JCGG-STR032527
Reactant Type
mannopyranoside
Mol
13.8 mmol
MOLECULE ID
JCGG-COM0000491
Reactant Type
AcOH (solvent)
Volume
38 mL
MOLECULE ID
JCGG-COM0000334
Reactant Type
H2SO4 (3 M in H2O)
Volume
12 mL
PRODUCT
MOLECULE ID
JCGG-COM0000298 (Reaction Tree)
Yield
42%
REACTION DETAIL
Reaction Time
4.5 hours
Reaction Temp
85 degree C
Solvent
AcOH
COMMENT
Keywords: synthesis, cleavage, methyl 2,3,4,6-tetra-O-benzyl-alpha-D-mannopyranoside
REFERENCE
Reference Id
REF-0000-000253
Source
Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
REF-0000-000254
Source
ISBN 978-3-527-31528-4
Reference Id
REF-0000-000256
Source
Liebigs Ann. Chem. 1249 (1983)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)