JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001824
Submitter
The Noguchi Institute
Reaction ID
R-0000-001824
Regist Date
2012/06/21 18:06:31
REACTANT
MOLECULE ID
JCGG-COM0002384 (Reaction Tree)
Reactant Type
L-fucose
Mol
60.9 mmol
PRODUCT
MOLECULE ID
JCGG-COM0002385 (Reaction Tree)
Skeleton
JCGG-STR032134
Yield
84%
REACTION DETAIL
Reaction Time
18 hours
Reaction Temp
reflux
Solvent
dry MeOH
Comment
10 g of strongly acidic ion exchange resin was included in the solvent.
COMMENT
Keywords: synthesis, methyl alpha-L-fucoside, Fischer glycosylation
REFERENCE
Reference Id
REF-0000-000253
Source
Essentials of Carbohydrate Chemistry and Biochemistry
Reference Id
REF-0000-000254
Source
ISBN 978-3-527-31528-4
Reference Id
REF-0000-000255
Source
J. Org. Chem. 37, 2141 (1972)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)