Reaction:JCGG-RAC0001822

JCGG ID

JCGG-RAC0001822

Submitter

The Noguchi Institute

Reaction ID

R-0000-001822

Regist Date

2012/06/21 18:05:44

REACTANT

MOLECULE ID

JCGG-COM0002380 (Reaction Tree)

Skeleton

JCGG-STR007916

Mol

0.93 mmol

MOLECULE ID

JCGG-COM0000802 (Reaction Tree)

Mol

1.86 mmol

MOLECULE ID

JCGG-COM0000129

Reactant Type

NIS

Mol

4.3 mmol

MOLECULE ID

JCGG-COM0000111

Reactant Type

TfOH

Mol

0.45 mmol

PRODUCT

MOLECULE ID

JCGG-COM0002381 (Reaction Tree)

Product Type

alpha

Yield

44%

REACTION DETAIL

Reaction Time

2 days

Reaction Temp

-15 degree C

Solvent

dry MeCN

Comment

56, 26, and MS 3A were mixed and stirred for 5 hours at room temperature before the reaction.

MS 3A was included in the solvent.

COMMENT

Keywords: synthesis, sialyl glycosides, ganglioside GT2 oligosaccharide

REFERENCE

Reference Id

REF-0000-000196

Source

PREPARATIVE CARBOHYDRATE CHEMISTRY

Reference Id

REF-0000-000197

Source

ISBN 0-8247-9802-3

Reference Id

REF-0000-000252

Source

J. Carbohydr. Chem. 14:491 (1995)