JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001821
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001821
Regist Date
 2012/06/21 18:05:20
REACTANT
MOLECULE ID
 JCGG-COM0002379 (Reaction Tree)
Skeleton
JCGG-STR003580
Mol
 0.26 mmol
MOLECULE ID
 JCGG-COM0000629 (Reaction Tree)
Mol
 0.53 mmol
MOLECULE ID
 JCGG-COM0000129
Reactant Type
 NIS
Mol
 1.1 mmol
MOLECULE ID
 JCGG-COM0000111
Reactant Type
 TfOH
Mol
 0.06 mmol
PRODUCT
MOLECULE ID
 JCGG-COM0002380 (Reaction Tree)
Skeleton
JCGG-STR007916
Product Type
 alpha
Yield
 45%
REACTION DETAIL
Reaction Time
 2 hours
Reaction Temp
 -30 degree C
Solvent
 dry MeCN
Comment
 55, 12, and MS 3A were mixed and stirred for 5 hours at room temperature before the reaction.
MS 3A was included in the solvent.
COMMENT
Keywords: synthesis, sialyl glycosides, ganglioside GM2 oligosaccharide
REFERENCE
Reference Id
 REF-0000-000196
Source
 PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
 REF-0000-000197
Source
 ISBN 0-8247-9802-3
Reference Id
 REF-0000-000252
Source
 J. Carbohydr. Chem. 14:491 (1995)
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)