JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001819
Submitter
The Noguchi Institute
Reaction ID
R-0000-001819
Regist Date
2012/06/21 18:04:23
REACTANT
MOLECULE ID
JCGG-COM0002375 (Reaction Tree)
Skeleton
JCGG-STR003580
Mol
0.82 mmol
MOLECULE ID
JCGG-COM0000802 (Reaction Tree)
Mol
1.6 mmol
MOLECULE ID
JCGG-COM0000129
Reactant Type
NIS
Mol
3.3 mmol
MOLECULE ID
JCGG-COM0000111
Reactant Type
TfOH
Mol
0.34 mmol
PRODUCT
MOLECULE ID
JCGG-COM0002376 (Reaction Tree)
Product Type
alpha
Yield
50%
REACTION DETAIL
Reaction Time
24 hours
Reaction Temp
-25 degree C
Solvent
dry MeCN
Comment
51, 26, and MS 3A were mixed and stirred for 5 hours at room temperature before the reaction.
MS 3A was included in the solvent.
COMMENT
Keywords: synthesis, sialyl glycosides, ganglioside GD2 oligosaccharide
REFERENCE
Reference Id
REF-0000-000196
Source
PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
REF-0000-000197
Source
ISBN 0-8247-9802-3
Reference Id
REF-0000-000249
Source
Carbohydr. Res. 252:283 (1994)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)