JCGG ID |
JCGG-RAC0001815 | |||||||
Submitter |
The Noguchi Institute | |||||||
Reaction ID |
R-0000-001815 | |||||||
Regist Date |
2012/06/21 18:02:52 | |||||||
REACTANT | ||||||||
|
|
|
||||||
Reactant Type |
acceptor | |||||||
Mol |
1.25 mmol | |||||||
|
|
|||||||
Reactant Type |
donor | |||||||
Mol |
2.49 mmol | |||||||
|
|
|||||||
Reactant Type |
NIS | |||||||
Mol |
4.98 mmol | |||||||
|
|
|||||||
Reactant Type |
TfOH | |||||||
Mol |
0.50 mmol | |||||||
PRODUCT | ||||||||
MOLECULE ID |
|
|
|
|||||
Product Type |
alpha | |||||||
Yield |
59% | |||||||
MOLECULE ID |
|
|
|
|||||
Product Type |
beta | |||||||
Yield |
10% | |||||||
REACTION DETAIL | ||||||||
Reaction Time |
2 hours | |||||||
Reaction Temp |
-35 degree C | |||||||
Solvent |
dry MeCN | |||||||
Comment |
19, 11, and MS 3A were mixed and stirred for 5 hours at room temperature before the reaction. | |||||||
MS 3A was included in the solvent. | ||||||||
COMMENT | ||||||||
Keywords: synthesis, sialyl glycosides, sialylation, penta-O-benzyl-lactose | ||||||||
REFERENCE | ||||||||
Reference Id |
REF-0000-000196 | |||||||
Source |
PREPARATIVE CARBOHYDRATE CHEMISTRY | |||||||
Reference Id |
REF-0000-000197 | |||||||
Source |
ISBN 0-8247-9802-3 | |||||||
Reference Id |
REF-0000-000244 | |||||||
Source |
J. Carbohydr. Chem. 10:493 (1991) | |||||||
Reference Id |
REF-0000-000246 | |||||||
Source |
J. Carbohydr. Chem. 11:699 (1992) |
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST) |