JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001813
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001813
Regist Date
 2012/06/21 18:02:46
REACTANT
MOLECULE ID
 JCGG-COM0002326 (Reaction Tree)
Skeleton
JCGG-STR031555
Mol
 2.6 mmol
MOLECULE ID
 JCGG-COM0002321 (Reaction Tree)
Mol
 5.2 mmol
MOLECULE ID
 JCGG-COM0000576
Reactant Type
 DMTST
Mol
 3.0 equiv. (relative to the donor)
PRODUCT
MOLECULE ID
 JCGG-COM0002327 (Reaction Tree)
Skeleton
JCGG-STR025493
Product Type
 alpha
Yield
 70%
REACTION DETAIL
Reaction Time
 17 hours
Reaction Temp
 -15 degree C
Solvent
 dry MeCN
Comment
 16, 11, and MS 3A were mixed and stirred for 6 hours at room temperature before the reaction.
MS 3A was included in the solvent.
The reactants were mixed at -30 degree in Celsius before stirred at -15 degree.
COMMENT
Keywords: synthesis, sialyl glycosides, sialylation, 3-O-benzoyl-galactose
REFERENCE
Reference Id
 REF-0000-000196
Source
 PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
 REF-0000-000197
Source
 ISBN 0-8247-9802-3
Reference Id
 REF-0000-000242
Source
 Carbohydr. Res. 184:C1 (1988)
Reference Id
 REF-0000-000243
Source
 Carbohydr. Res. 212:277 (1991)
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)