JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001794
Submitter
The Noguchi Institute
Reaction ID
R-0000-001794
Regist Date
2012/06/21 17:57:17
REACTANT
MOLECULE ID
JCGG-COM0002345 (Reaction Tree)
Skeleton
JCGG-STR025493
Reactant Type
sugar
MOLECULE ID
JCGG-COM0000086
Reactant Type
Ac2O
MOLECULE ID
JCGG-COM0000099
Reactant Type
BF3*OEt2
MOLECULE ID
JCGG-COM0000565
Reactant Type
TMSSMe
MOLECULE ID
JCGG-COM0000009
Reactant Type
TMSOTf
PRODUCT
MOLECULE ID
JCGG-COM0002346 (Reaction Tree)
Yield
NOT specified
REACTION DETAIL
Reaction Time
NOT specified, NOT specified
Reaction Temp
NOT specified, NOT specified
Solvent
NOT specified, NOT specified
Comment
1) sugar+Ac2O, BF3*OEt2, 2) +TMSSMe, TMSOTf
Very few were described regarding this reaction.
COMMENT
Keywords: synthesis, sialyl glycosides, systematic synthesis, gangliosides, sialyloligosaccharides, sialyl galactose
There are multiple steps in this reaction.
The reaction is the 2nd part of the sequence.
REFERENCE
Reference Id
REF-0000-000196
Source
PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
REF-0000-000197
Source
ISBN 0-8247-9802-3

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