JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
 JCGG-RAC0001792
Submitter
 The Noguchi Institute
Reaction ID
 R-0000-001792
Regist Date
 2012/06/21 17:57:00
REACTANT
MOLECULE ID
 JCGG-COM0000818 (Reaction Tree)
Reactant Type
 sugar
MOLECULE ID
 JCGG-COM0000086
Reactant Type
 Ac2O
MOLECULE ID
 JCGG-COM0000099
Reactant Type
 BF3*OEt2
MOLECULE ID
 JCGG-COM0000565
Reactant Type
 TMSSMe
MOLECULE ID
 JCGG-COM0000009
Reactant Type
 TMSOTf
PRODUCT
MOLECULE ID
 JCGG-COM0002343 (Reaction Tree)
Yield
 NOT specified
REACTION DETAIL
Reaction Time
 NOT specified, NOT specified
Reaction Temp
 NOT specified, NOT specified
Solvent
 NOT specified, NOT specified
Comment
 1) sugar+Ac2O, BF3*OEt2, 2) +TMSSMe, TMSOTf
Very few were described regarding this reaction.
COMMENT
Keywords: synthesis, sialyl glycosides, systematic synthesis, gangliosides, sialyloligosaccharides, sialyl galactose
There are multiple steps in this reaction.
The reaction is the 2nd part of the sequence.
REFERENCE
Reference Id
 REF-0000-000196
Source
 PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
 REF-0000-000197
Source
 ISBN 0-8247-9802-3
©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)