JCGGDB TOP Glycan Syntheses

Reaction

JCGG ID
JCGG-RAC0001761
Submitter
The Noguchi Institute
Reaction ID
R-0000-001761
Regist Date
2012/06/21 17:53:12
REACTANT
MOLECULE ID
JCGG-COM0002311 (Reaction Tree)
Skeleton
JCGG-STR032397
Mol
13.5 mmol
MOLECULE ID
JCGG-COM0001650
Reactant Type
Br2 (2.5 M in CH2Cl2)
PRODUCT
MOLECULE ID
JCGG-COM0002312 (Reaction Tree)
Yield
NOT specified
REACTION DETAIL
Reaction Time
until a faint yellow color persisted
Reaction Temp
0 degree C
Solvent
dry CH2Cl2
COMMENT
Keywords: oligosaccharide synthesis, n-pentenyl glycosides, 1,2-Orthoesters, Glycosyl Bromides, Coupling, Koenigs-Knorr Procedure
The reaction is the 1st part of the sequence.
REFERENCE
Reference Id
REF-0000-000196
Source
PREPARATIVE CARBOHYDRATE CHEMISTRY
Reference Id
REF-0000-000197
Source
ISBN 0-8247-9802-3
Reference Id
REF-0000-000236
Source
J. Am. Chem. Soc. 117:1546 (1995)

©2008-2013 Research Center for Medical Glycoscience, National Institute of Advanced Industrial Science and Technology (AIST)